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  • 雅瑞化工

    YaRuiChem

    Zhang Jia Gang YaRui Chemical Co., Ltd.

    Mainly export of phosphate ester flame retardants and polyurethane
    curing chain extenders, supplemented by domestic sales

    Location: Home > Products > Curing Agent|Chain Extender > Dimethylthiotoluene Diamine|DMTDA|E300

    Dimethylthiotoluene Diamine|DMTDA|E300

    Dimethylthiotoluene Diamine,DMTDA,E300 is an environmentally friendly low-toxic liquid diamine chain extender, mainly used in polyurethane elastomers, RIM (reactive injection molding), SPUA (sprayed polyurea elastomer) and adhesives, and can also be used as epoxy resin curing It has been widely used in polyurethane rubber rollers, medicine, stamping and molding, etc. In addition, it is widely used in automobiles, metal mines, textiles, papermaking, and printing industries. It is a new type of polyurethane elastomer curing crosslinking agent. , Equivalent to Ethancure 300.

     

    ★ Basic elements of the product

    Appearance: light yellow to amber transparent liquid

    Cas No: 106264-79-3

    Dimethylthiotoluene Diamine,DMTDA,E300 Packing: 200KG / galvanized iron drum, 1000KG / IB drum

    • Product description
    • Product Quality Checklist
    • Product Process
    • COA,TDS,MSDS

     1. Product physical properties

    Chinese name dimethylthiotoluene diamine, curing agent chain extender DMTDA
    English name: Dimethyl Thio-Toluene Diamine
    Appearance: yellow to amber transparent liquid at room temperature
    Content:》 99%
    Water content: ≤0.1%
    Density: 1.206 (20 ℃)
    Boiling point: 200 ℃ (1.68mmHg)
    Viscosity: 600-900 mPa · s (25 ℃)
    Vapor pressure (mmHg) max 0.01 (20 ℃)

    Packing: Net weight 200KG / galvanized iron barrel (16 tons in a small cabinet), 1000KG / IB barrel (18 tons in a small cabinet) or 23 tons of ISOTANK.

     

    2. Product Technical Index

    Test items Enterprise testing index Test results
    Appearance Light yellow transparent liquid Light yellow transparent liquid
    Chromaticity Platinum-Cobalt Colorimetry       ≤500      300
    Dimethylthiotoluenediamine (2,4-plus 2,6)       ≥96       97
    A methylthio toluenediamine       ≤4.0       2.3
    Three group toluenediamine       ≤1.0       0.2
    Water       ≤0.1%      0.05

    Amine value(mgKOH/g)

     

         525-535      529

    3. Product use and product advantages

    A new type of polyurethane elastomer curing crosslinking agent, in which there are mainly two isomers, a mixture of 2,4- and 2,6-dimethylthiotoluenediamine (ratio is about 77 ~ 80/17 ~ 20 ), Compared with the commonly used MOCA, it is a liquid with a low viscosity at normal temperature, which can be applied to the construction operation at low temperature, and has the advantages of low chemical equivalent.
    Dimethylthiotoluene diamine-curing agent chain extender DMTDA is a new type of polyurethane elastomer curing crosslinking agent, which is equivalent to Ethancure 300. There are two main isomers, namely 2,4- and 2,6- A mixture of methylthiotoluene diamine (ratio about 77 ~ 80/17 ~ 20), compared with the commonly used MOCA, it is a low viscosity liquid at room temperature, which can be suitable for operation at low temperature, low chemical equivalent, etc. advantage. DMTDA is an environmentally friendly, low-toxic liquid diamine chain extender, mainly used in polyurethane elastomers, RIM (reactive injection molding), SPUA (sprayed polyurea elastomer) and adhesives; it can also be used for epoxy resin curing The agent has been widely used in polyurethane rubber rollers, medicine, stamping and forming.In addition, it has been widely used in automobiles, metal mines, textiles, papermaking, and printing industries.

     

    The curing agent chain extender DMTDA curing speed is much slower than DETDA, and can be mixed with DETDA in different proportions to adjust the curing speed to meet different needs.
    1. Dimethylthiotoluenediamine-DMTDA hindered aromatic diamine, the steric hindrance of methylthio and methyl makes its activity lower than TDA and DETDA, and its reaction rate with prepolymer is longer than DETDA5 -9 times.
    2. The activity of dimethylthiotoluene diamine-curing agent chain extender DMTDA is higher than that of MOCA, and the pouring time for curing with dimethylthiotoluene diamine-curing agent chain extender DMTDA in the prepolymer with low NOC content Shorter than MOCA, it is more suitable for workers to operate and improve production efficiency.
    3. The curing temperature can be reduced to room temperature (the preheating temperature can be adjusted within the range of 25 degrees to 100 degrees)
    4. The low equivalent weight is 107 (MOCA is 133.5), and the consumption of the same amount of cured prepolymer is low to reduce the cost.
    5. The performance and alkali resistance of the synthetic PU (polyurethane) is better than that of MOCA cured products, and the injection type elastomer has a better effect.
    6. MOCA needs high temperature during curing to volatilize carcinogens, but DMTDA will not volatilize carcinogens at room temperature. It is an internationally recognized environmentally friendly chain extender (curing agent).
    7.Compared with the traditional curing agent MOCA, dimethylthiotoluene diamine-DMTDA has many advantages: it is liquid at room temperature, easy to use, and can be cured at room temperature; the mechanical properties of the cured product are comparable to MOCA and comparable foreign products The physical and mechanical properties are basically the same, and the price is lower, which can reduce the cost of the product, so this product is an ideal substitute for traditional curing agents.

     

    4.Dimethylthiotoluene diamine-curing agent chain extender DMTDA processing performance and performance:

    Dimethylthiotoluenediamine-DMTDA is a low-viscosity liquid at room temperature. It has good fluidity. Therefore, it provides flexibility for the temperature at which the prepolymer is mixed with the curing agent. According to this, it There are also the following advantages:
    1. Good compatibility with other components;
    2. When the NCO% content in the prepolymer is low, it requires a shorter curing time than MOCA, which is more beneficial to the operator.
    3. When the NCO% content in the prepolymer is large, it needs to be cured due to the high reactivity, which takes a long time, which is especially beneficial to the operator.
    4. At the same NCO% content, the equivalent value of DMTDA (107) is smaller than that of MOCA (133.5), therefore, its dosage is less than MOCA.

     

    5.The difference between the curing agent chain extender DMTDA dimethylthiotoluene diamine, foreign products ETHACUR E300, MOCA:

    Project

    DMTDA

    ETHACURE300

    MOCA

    Standard test

    NHz/ NCO

    0.97

    0.97

    0.95

     

    Post-ripening

    16/85

    16/85

    16/100

     

    Hardness / Shore A

    89

    93

    91

    GB/ T531一92

    Tensile strength / kgcm-Z

    540

    7710 (psi )

    460

    GB/ T528一92

    100 stress / kgcm-Z

    6.3

    1080 (psi )

    7.0

    GB/ T528一92

    Tear strength / kNm-1

    105

    120

    115

    GB/T529-91

    Elongation/%

    750

    600

    600

    GB/ T528一92

    Resilience /%

    45

    32

    40

    GB/T1681--1

     

    1. The resulting dimethylthiotoluene diamine-curing agent chain extender DMTDA product has a higher viscosity at room temperature than ETHACU RE300. It is known that when manufacturing polyurethane elastomers, whether it is a pre-polymerization method or a semi-pre-polymerization method, pre-polymerization The components of the substance have a high viscosity. When the two components are mixed, the viscosity is easier to mix evenly; and generally the two components must be insulated. Even if they are mixed and cured at room temperature, the viscosity of the product will not have any effect on the process. Impact, so a relatively high viscosity has no effect on its application.
    2. The appearance is darker than ETHACURE300. This is the shortcoming of this product, which limits the application of this product in polyurethane cool light-colored products. In this regard, further improvement is needed.
    3. The performance of the elastomer obtained by the product is completely comparable to that of MOCA, and some properties have been improved; in this respect, it has completely reached the level of similar foreign products.

    Product name Dimethylthiotoluene diamine
    Production Date March 1, 2015
    Quantity 5000KG
    Lot number March 1, 2015
    Project Standard Test results
    Appearance Light yellow thick liquid Light yellow thick liquid
    Diamine content% ≥99 99.52
    TDA  content% ≤1.00 0.001
    Amine value mgKOH / g 520-540 530
    Moisture% ≤0.10 0.06
    Color value 6.9 6.1

    Essential information for product export:

    Chinese name dimethylthiotoluene diamine, curing agent chain extender DMTDA
    English name: Dimethyl Thio-Toluene Diamine
    Appearance: yellow to amber transparent liquid at room temperature
    Tax refund: 17%
    UN: 3082
    CAS No.:106264-79-3
    Customs Code HS: 29309090.90
    Several types of dangerous goods: 9 types of dangerous goods exported
    DMTDA raw materials: toluene diamine (TDA) and dimethyl disulfide (DMDS)
    Packing: Net weight 200KG / galvanized iron barrel (16 tons in a small cabinet), 1000KG / IB barrel (18 tons in a small cabinet) or 23 tons of ISOTANK.

    HONORS

    Outstanding private enterprise in Jiangsu Province
    Jiangsu Credit Integrity Brand Enterprise
    Jiangsu Top Ten Advanced Customer Satisfaction Advanced Enterprise
    Jiangsu Province Quality and Safety Qualified Units
    Jiangsu Province Green Environmental Protection Technology Innovation Enterprise
    ISO-9001-Quality Management System Certification
    Jiangsu AAA quality, service and integrity enterprise
    Jiangsu Province Quality and Safety Management AAAAA Brand Enterprise

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